Enhanced daytime atmospheric mercury in the marine boundary layer in the South Oceans.

Understanding the spatial and temporal variations of atmospheric mercury (Hg) in the marine boundary layer could advance our knowledge on ocean evasion of Hg. Here, we conducted continuous measurements of total gaseous mercury (TGM) in the marine boundary layer during a round-the-world cruise from August 2017 to May 2018. We observed the highest and lowest TGM concentrations in Southern Indian Ocean (1.29 ± 0.22 ng m-3) and Southern Atlantic Ocean (0.61 ± 0.28 ng m-3), respectively. During the daytime, enhanced TGM was observed with the diurnal amplitude difference reaching its maximum in the range of 0.30-0.37 ng m-3 in Southern Indian Ocean and Southern Ocean. The positive correlation between TGM (R2 = 0.68-0.92) and hourly solar radiation in each ocean suggested that the daytime enhanced TGM was likely driven by Hg photoreduction in seawater, after excluding the influence of other meteorological factors. The diurnal amplitude of TGM in the marine boundary layer might be impacted by the microbial productivity and the ratio of ultraviolet radiation. Our study highlights that ocean acts as a net TGM source during the daytime in the Southern Hemisphere and aqueous photoreduction process may play an important role in the biogeochemical cycling of Hg.