In-depth analysis of embedded-type structures of NixMg4-xAl LDO-composited catalysts and the impacts on glycerol conversion under a base- and H2-free condition

Core-shell composite catalysts composing of AgO@SnO2/ZSM-5 embedded by NixMg4-xAlO LDOs with various Ni/Mg ratios were characterized and tested for the activity on the conversion of glycerol to valuable chemicals under a base-free and external H2-free condition. As a result, the catalytic performance of an embedded composite was found greater than that of its individual constituents, owing to the synergy between a NixMg4-xAlO lodge and embedded AgO@SnO2/ZSM-5. The highest yield of 1,2-propanediol and lactic acid was achieved at the Ni/Mg ratio of 0.2/3.8. NixMg4-xAlO lodges were found to simultaneously drive glycerol dehydration to acetol and glycerol reforming, driven by Ni sites, forming in-situ H2 that enhances 1,2-propanediol formation whereas the AgO@SnO2/ZSM-5 clusters governed acetol oxidation and Cannizzaro reaction that led to the formation of lactic acid. At a high Ni/Mg ratio, the NixMg4-xAlO lodges completely covered AgO@SnO2/ZSM-5 clusters entirely, resulting in the suppression of lactic acid yield due to over-oxidation.