MOF-templated tubular Ni1-xCoxS2-CdS heterojunction with intensified direct Z-scheme charge transmission for highly promoted visible-light photocatalysis

Hollow semiconductor nanostructures with direct Z-scheme heterojunction have significant advantages for photocatalytic reactions, and optimizing the interfacial charge transmission of Z-scheme heterojunction is the hinge to achieve excellent solar conversion efficiency. In this work, tubular Ni1-xCoxS2-CdS heterostructures with reinforced Z-scheme charge transmission were constructed through an In-metal-organic framework (MOF) templated strategy. The Z-scheme charge transfer mechanism was sufficiently confirmed by combining density functional theory (DFT) calculation, X-ray photoelectron spectroscopy (XPS), surface photovoltage spectroscopy (SPV), and radical testing results. Crucially, the use of sodium citrate complexant contributes to the formation of intimate heterointerface, and the Fermi level gap between CdS and NiS2 is enlarged through Co doping into NiS2, which enhances the built-in electric field and photo-carriers transmission driving force for Ni1-xCoxS2-CdS heterojunction, resulting in an evidently promoted activity toward H2 evolution reaction (HER). Under visible-light (λ > 400 nm) irradiation, the Ni1-xCoxS2-CdS composite with 10 mol