2D MXene incorporated nickel hydroxide composite for supercapacitor application

P. E. Lokhande,Chaitali Jagtap,Vishal Kadam, R. Udayabhaskar,Deepak Kumar,Bandar Ali Al-Asbahi, Yedluri Anil Kumar

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS(2024)

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摘要
In the current investigation, we report the successful synthesis of a novel Ni(OH)2/Ti3C2Tx MXene nanocomposite via a microwave-assisted technique, specifically tailored for supercapacitor applications. The inherent semiconductor properties of nickel hydroxide often impede its electrochemical capabilities; however, the integration with a conductive host material can significantly ameliorate this limitation. To this end, Titanium Carbide (Ti3C2Tx) was incorporated during the Nickel Hydroxide (Ni(OH)2) synthesis process, resulting in the in-situ formation of Ni(OH)2 nanosheets homogeneously anchored onto the MXene sheets. The electrode derived from this nanocomposite showcased exceptional electrochemical attributes. Notably, it achieved a remarkable-specific capacitance peak of 675 Fg-1 at a current density of 2 Ag-1, coupled with outstanding stability and cyclability metrics. Furthermore, the asymmetric supercapacitor engineered with the synthesized material attained an energy density of 9.25 Whkg-1 and a power density of 3.2 kWkg-1. This device not only demonstrated superior rate capability but also sustained cyclic stability. The empirical evidence gathered from these experiments underscores the promising potential of metal hydroxide/MXene nanocomposites in advancing supercapacitor technology.
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