Ultrasonic Fortification of Interfiber Autohesive Contacts in Meltblown Nonwoven Materials

Autohesion is a unique class of adhesion that enables the bonding of two identical surfaces by establishing intimate contact at interfaces. Creating intimacy between two identical surfaces poses a challenging task, often constrained by the presence of surface roughness and chemical heterogeneity. To surmount this challenge, we document a variety of autohesive traits in polypropylene-based melt-blown nonwovens, accomplished through a facile, scalable, energy-efficient, and cost-effective ultrasonic bonding process. The mean work of autohesion for a single polypropylene bond, serving as a figure of merit, has been computed by extending the classical Johnson−Kendall−Roberts (JKR) theory by factoring in peel strength along with key fiber and structural parameters of nonwoven materials. Achieving a high figure of merit in ultrasonically bonded nonwovens hinges on the synergistic interplay of key process parameters, including static force, power, and welding speed, with the fiber and structural properties acting in concert. In this regard, peel-off force analysis has also been conducted on a series of twenty-seven ultrasonically bonded melt-blown nonwovens prepared using a 33 full factorial design by systematically varying process parameters (static force, power, and welding speed) across three levels and extension rate. X-ray microcomputed tomography (microCT) analysis has been performed on select ultrasonically bonded nonwoven samples to discern their bulk characteristics. A broad spectrum of mean work of autohesion for a single polypropylene bond, ranging from 1.88 to 9.93 J/m², has been ascertained by modulating key process parameters.