Hygrothermal progressive damage in open-hole compression of composite laminates with aligned carbon nanotube interlaminar reinforcement studied by X-ray micro-computed tomography

Hierarchical nanoengineered composite laminates were created with through-thickness-aligned carbon nanotube (CNT) reinforcement of unidirectional carbon (micro) fiber/epoxy laminae in their failure-prone interlaminar regions, forming a multiscale “nanostitched” architecture. Motivated by previous mechanical enhancements for similar nanostitched laminates in ambient environments, hygrothermal effects on the 3D strengthening and toughening mechanisms of nanostitched laminates are investigated here for the first time, focusing on standard open-hole compression (OHC) testing of quasi-isotropic laminates. We report that the hygrothermal conditions of −55 °C/DRY and 100 °C/DRY correspond to ultimate strength increases of 2.6% and 5.9%, respectively, for nanostitched laminates over the baseline; and, room temperature/50% relative humidity (RT/50% RH) and 100 °C/wet conditions exhibit no change in ultimate strength, suggesting correlation of positive nanostitch effects with increased polymer brittleness. Subsequently, damage progression in step-wise interrupted OHC loading for selected hygrothermal conditions (RT/50% RH and 100 °C/DRY) was performed in coordination with high-resolution ex situ X-ray micro-computed tomography for various load steps up to 98% of failure load. No clear differences due to nanostitch in the damage progression are found up to 98% of ultimate strength, suggesting that the reinforcement effect is associated with interlaminar strength at ultimate load, and not pre-ultimate damage. This study contributes first insights from high-resolution experimental mapping of nanostitched composite progressive damage subjected to hygrothermal conditions that may guide and inform mechanical enhancement approaches and improved progressive damage models. Future work is suggested to expand the environmental conditions considered, as well as visualize progressive damage nearer to failure to identify nanostitch effects on complex multimodal failure.