Mesoscopic combinatorial design of anisotropic graphitic carbon with ordered porous frameworks for thermoelectric conversion

The incorporation of carbon materials can effectively enhance the performance of thermoelectric materials. By optimizing the thermoelectric properties of the carbon scaffold, it is possible to further improve the thermoelectric performance of the prepared carbon-based composites. To elevate the thermoelectric performance of the carbon scaffold, this work introduces a novel mesoscopic design strategy, utilizing natural flake graphite to create a three-dimensional ordered porous framework. Highly controllable anisotropic conductivity and thermal conductivity of the porous graphite skeleton were achieved, by combining sizable sodium chlorine templates (37.5–250 μm) with a natural flake graphite matrix (50–150 μm). A porous graphite with high electrical conductivity and low thermal conductivity along the vertical axis was obtained by carefully regulating the parameters. The sample demonstrated exceptional thermoelectric conversion performance, achieving a thermoelectric power factor of 12.2 μW·m−1 K−2 and a figure of merit value of 28.3 × 10−4. Furthermore, the thermoelectric property of the samples could be greatly improved by adding a small amount of ferric chloride, with a thermoelectric power factor reaching 41.9 × 10−4 and a thermoelectric figure of merit reaching 81.4 μW·m−1 K−2. This work provides an effective scheme for the mesoscopic regulation of porous graphite carbon structures and offers a new strategy for enhancing the performance of thermoelectric generators.