Observation of in-gap states in a two-dimensional CrI2/NbSe2 heterostructure

Low-dimensional magnetic structures coupled with a superconductor are promising platforms for realizing Majorana zero modes, which are considered as novel non-Abelian anyons with potential applications in topological quantum computing. Here, we report the observation of in-gap edge states and zero-bias conductance peaks (ZBCPs) in a two-dimensional (2D) magnetic-superconducting heterostructure consisting of a single-layer chromium diiodide (CrI2) on a niobium diselenide (NbSe2) superconductor. Single-layer CrI2 nanosheets, which hold antiferromagnetic (AFM) ground states according to our first-principles calculations, were epitaxially grown on the layered NbSe2 substrate. By using scanning tunneling microscopy/spectroscopy, we observed robust in-gap states spatially located at the edge of the nanosheets and defect-induced ZBCPs inside the CrI2 nanosheets. Magnetic-flux vortices induced by an external field exhibit broken threefold rotational symmetry of the pristine NbSe2 superconductor, implying the efficient modulation of the interfacial superconducting states by the epitaxial CrI2 layer. A phenomenological model was proposed and suggested the existence of chiral edge states in a 2D AFM-superconducting hybrid system with an even Chern number, providing a qualitatively plausible understanding for our experimental observation.