The highest gas hydrate volume estimate found in the sediments of the Chilean margin

Along the Chilean continental margin, where the active Nazca plate subducts under the South American plate, large deposits of gas hydrates trapped in marine sediments can be observed in seismic profiles (from Valparaíso to Patagonia), which may be affected by the increase in deep-water temperature due to climate change. This could trigger a massive release of methane gas into the marine environment and the atmosphere with negative effects on the environment, mainly through dissociation of the hydrates and/or direct migration to the seafloor through faults. In this study, new multichannel seismic data located off Chiloé Island (∼42°S) are presented, and for the first time a BSR parallel to the continental margin (north-south) is analysed. Here, an efficient sediment subduction occurs where the young oceanic Nazca plate (5-25 Ma) subducts beneath the continental plate along Chiloé Island. In addition, an integrated analysis to better understand the hydrological and hydrothermal system in this area included previous geophysical and geological datasets, such as a) bathymetry, b) geothermal gradient calculated from gas hydrate distribution boundaries, and c) thermal conductivities.  The results show a continuous and strong BSR along the entire seismic profile MGL1701-27 (approximately 27 km long), where large deformations, fractures and faults occur, favouring the flow of carbon-rich fluids from the depths, which subsequently form the gas hydrate layer. The large amount of gas hydrate present in the marine sediments off the coast of Chiloé Island is impressive. Velocity analysis of seismic profile MGL1701-27 indicates gas hydrate concentration values of up to 25% of the total rock volume, the highest estimates obtained at the Chilean margin. In addition, a peak in the geothermal gradient is related to deep faults that allow the passage of hot fluids from deeper strata to the seafloor.  Finally, a large amount of free gas is estimated beneath the BSR, which enhances its intensity and continuity in the seismic profile. Our results provide valuable information for current and future studies related to climate change (methane storage), hydrothermal circulation, seismicity, gas hydrate stability and fluid venting in this natural laboratory, since Chiloé Island is located at the southern boundary of the rupture zone of the largest earthquake in recorded history (the Mw 9.5 Valdivia earthquake), the implications of which have yet to be fully elucidated.