The core-shell CuO/PDA@TA-Fe nanowires arrays on 3D Cu foam for solar evaporator and water purification with highly efficiency and stability

Wei Zhang, Gang Xue,Weiting Zhan, Lu Han, Yujian Liu, Likun Liu,Hongwei Ni,Hongbo Zeng

Surfaces and Interfaces(2024)

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摘要
Photothermal nanomaterials can provide a viable solution to tackle water pollution and water shortage. However, the material design of photothermal nanomaterials with highly efficiency and stability presents a significant technical challenge. In this paper, functional high-efficient 3D solar evaporators were prepared on 3D copper foam with self-support CuO nanowires arrays, which are successfully coated by ultrathin PDA@TA-Fe nanofilms for making core-shell CuO/PDA@TA-Fe nanowires arrays. Under stimulated 1 sunlight irradiation, the core-shell CuO/PDA@TA-Fe nanowires arrays exhibited a high solar-driven water evaporation rate of 1.932 Kg·m−2·h−1 with evaporation efficiency of 92 %. The core-shell CuO/PDA@TA-Fe nanowires arrays demonstrated a relatively stable mass change after 10 cycles indicating the stability of this evaporator system. The evaporators were studied as solar-driven photocatalysis for photodegradation of organic waste in dye wastewater and presented high evaporation efficiency (91.6 %) in 3.5wt% NaCl solution under sunlight irradiation. Therefore, the core-shell CuO/PDA@TA-Fe nanowires arrays provided a new research direction for the development of solar water purification system with highly efficient and stability for a wide applications of future seawater purification and wastewater treatment.
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关键词
Photothermal conversion,Solar evaporation,Photocatalysis,Water purification,Desalination
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