Tailoring Multiple Strengthening Phases to Achieve Superior High-Temperature Strength in Cast Mg-RE-Ag Alloys

Sicong Zhao,Erjun Guo,Kun Liu,Jingfang Li, Jianhua Liu, Mingyang Li

MATERIALS(2024)

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摘要
Mg alloys with excellent high-temperature mechanical properties are urgently desired to meet the design requirements of new-generation aircraft. Herein, novel cast Mg-10Gd-2Y-0.4Zn-0.2Ca-0.5Zr-xAg alloys were designed and prepared according to the advantages of multi-component alloying. The SEM and XRD results revealed that the as-cast microstructures contained alpha-Mg grains, beta, and Zr-containing phase. As Ag rose from 0 wt.% to 2.0 wt.%, the grain size was refined from 40.7 mu m to 33.5 mu m, and the beta phase significantly increased. The TEM observations revealed that the nano-scaled gamma ' phase could be induced to precipitate in the alpha-Mg matrix by the addition of Ag. The stacking sequence of lamellar gamma ' phases is ABCA. The multiple strengthening phases, including beta phase, gamma ' phases, and Zr-containing particles, were effectively tailored through alloying and synergistically enhanced the mechanical properties. The ultimate tensile strength increased from 154.0 +/- 3.5 MPa to 231.0 +/- 4.0 MPa at 548 K when Ag was added from 0 to 2.0 wt.%. Compared to the Ag-free alloy, the as-cast alloy containing 2.0 wt.% Ag exhibited a minor reduction in ultimate tensile strength (7.0 +/- 4.0 MPa) from 498 K to 548 K. The excellent high-temperature performance of the newly developed Mg-RE-Ag alloy has great value in promoting the use of Mg alloys in aviation industries.
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关键词
Mg alloys,precipitates,high-temperature performance,strengthening mechanism
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