Non-alloyed ohmic contacts to (010) -Ga2O3 with low contact resistance

Kathleen T. Smith, Cameron A. Gorsak, Avijit Kalra, Bennett J. Cromer,Kathy Azizie, Daniel M. Dryden,Darrell G. Schlom,Debdeep Jena,Hari P. Nair,Huili Grace Xing

APPLIED PHYSICS LETTERS(2023)

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摘要
Low resistance non-alloyed ohmic contacts are realized by a metal-first process on homoepitaxial, heavily n(+) doped (010) beta-Ga2O3. The resulting contacts have a contact resistance (R-c) as low as 0.23 Omega-mm on an as-grown sample and exhibit nearly linear ohmic behavior even without a post-metallization anneal. The metal-first process was applied to form non-alloyed contacts on n(+) (010) beta-Ga2O3 grown by metal-organic chemical vapor deposition (MOCVD) as well as suboxide molecular beam epitaxy. Identical contacts fabricated on similar MOCVD samples by conventional liftoff processing exhibit highly rectifying Schottky behavior. Re-processing using the metal-first process after removal of the poor contacts by conventional methods does not improve the contacts; however, addition of a Ga-flux polishing step followed by re-processing using a metal-first process again results in low resistance, nearly linear ohmic contacts. The liftoff process, therefore, does not reliably render nearly linear ohmic behavior in non-alloyed contacts. Furthermore, no interface contamination was detected by x-ray photoelectron spectroscopy. This suggests that during the initial liftoff processing, a detrimental layer may form at the interface, likely modification of the Ga2O3 surface, that is not removable during the contact removal process but that can be removed by Ga-flux polishing.
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