"Beyond conventional energy applications: Exploring the superiority of NiCu-MOF/NbS2//CNT-doped activated carbon for Supercapattery and oxygen evolution reactions"

DIAMOND AND RELATED MATERIALS(2024)

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摘要
Numerous investigations were conducted to produce effective electrode materials for applications such as energy storage and oxygen evolution reaction (OER). Bimetallic NiCu-MOF/NbS2 was synthesized and applied in supercapattery devices in this study. The NiCu-MOF/NbS2 electrode in a three-cell investigation revealed a specific capacity (Qs) of 1507C/g at a current density of 2.0 A/g. The Brunauer-Emmett-Teller (BET) measurement indicated a high specific surface area of 46 m2/g, which causes enhancement in the electrochemical per-formance. The supercapattery device (NiCu-MOF/NbS2) was also built using NiCu-MOF/NbS2 with CNT@activated carbon which showed a Qs of 194C/g. It had an energy density of 83 Wh/kg and a power density of 970 W/kg. The NiCu-MOF/NbS2 device can retain 97 % capacity retention after 20,000 GCD cycles. The NiCu-MOF/NbS2 was also tested in an oxygen evolution reaction and showed the least overpotential of 175 mV composite. The NiCu-MOF/NbS2 electrode had significant potential for energy storage devices and in OER applications.
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关键词
BimetallicNiCu-MOF/NbS2,Supercapattery,Oxygen evolution reaction,Electrocatalytic activity,Next-generation energy storage system
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