In situ Implanting 3D Carbon Network Reinforced Zinc Composite by Powder Metallurgy for Highly Reversible Zn-based Battery Anodes

Aqueous Zn-based batteries have emerged as compelling candidates for grid-scale energy storage, owing to their intrinsic safety, remarkable theoretical energy density and cost-effectiveness. Nonetheless, the dendrite formation, side reactions, and corrosion on anode have overshadowed their practical applications. Herein, we present an in situ grown carbon network reinforcing Zn matrix anode prepared by powder metallurgy. This carbon network provides an uninterrupted internal electron transport pathway and optimize the surface electric field distribution, thereby enabling highly reversible Zn deposition. Consequently, symmetrical cells demonstrate impressive stability, running for over 880 h with a low voltage hysteresis (approximate to 32 mV). Furthermore, this Zn matrix composite anode exhibits enhanced performance in both the aqueous Zn-ion and the Zn-air batteries. Notably, Zn//MnO2 cells display superior rate capabilities, while Zn-air batteries deliver high power density and impressive Zn utilization rate (84.9 %). This work provides a new idea of powder metallurgy method for modified Zn anodes, showcasing potential for large-scale production. Our work provides a novel understanding of in situ implanted carbon network reinforcing Zn anode by powder metallurgy, moving from the surface/interface modification of Zn foil to the bulk phase regulation of Zn powder. The carbon network as an electron transport channel enhances the conductivity of the electrode and provides more nucleation sites to inhibit the growth of dendrites, realizing a highly reversible Zn anode.image