CRACKING OPTIMIZATION OF PALMITIC ACID USING Fe3+ MODIFIED NATURAL MORDENITE FOR PRODUCING AVIATION FUEL COMPOUNDS

CHEMISTRY & CHEMICAL TECHNOLOGY(2023)

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摘要
Natural mordenite from Turen village Malang district Indonesia has been modified to Fe3+-mordenite for heterogenous catalyst in cracking process of palmitic acid to produce Aviation fuel components. Cation exchange method has been used in mordenite modification using FeCl3. The Fe3+-mordenite was characterized by structure analysis, Fe content, Si/Al ratio, number of acid sites, pore size, pore volume, and surface area. The catalytic per-formances, conversion, and selectivity were measured at 583 K by GC-MS for 1, 2, and 3 hours. The high content of Fe in mordenite has larger Bronsted-Lewis's acid site, pore volume and surface area than the natural mordenite. The crystal structure of Fe3+-mordenite is still the same with natural mordenite. The Fe3+-mordenite also has a smaller pore size than the natural mordenite. In cracking process of palmitic acid, Fe3+-mordenite performed 61.94 % of conversion and 92.90 %, which produced aviation fuel compounds, namely alkanes, alkene, cycloalkane and aromatic.
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关键词
cycloalkane aviation fuel,mordenite,cation exchanged,acid site,palmitic acid
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