Cover Picture: Enforced Electronic‐Donor‐Acceptor Complex Formation in Water for Photochemical Cross‐Coupling (Angew. Chem. Int. Ed. 17/2023)

The sugar alcohol meglumine enhances the solubility of organic compounds in water and enforces the formation of electron donor–acceptor (EDA) complexes, enabling photochemical C−C and C−S cross-coupling transformations without sensitizers. The light-driven redox-neutral protocol connects haloarenes with indoles, anilines, anisoles, and thiols, as reported by Burkhard König and co-workers in their Research Article (e202218775). The sugar alcohol meglumine enhances the solubility of organic compounds in water and enforces the formation of electron donor–acceptor (EDA) complexes, enabling photochemical C−C and C−S cross-coupling transformations without sensitizers. The light-driven redox-neutral protocol connects haloarenes with indoles, anilines, anisoles, and thiols, as reported by Burkhard König and co-workers in their Research Article (e202218775). Carbenes Solar Cells CO2 Reduction