MIEX resin and enhanced coagulation treatment of high-bromide natural water: Chlorine reactivity and DBP precursors removal

Both organic and inorganic constituents play a major role in the formation and speciation of disinfection byproducts (DBPs) under chlorination. In this study, the removal of organic and inorganic precursors to DBPs by ion exchange and coagulation was examined, and the relationships between characteristics of dissolved organic matter (DOM), chlorine reactivity, and the formation of DBPs in high-bromide natural water were investigated. Formation potential tests were conducted for trihalomethanes (THMs) and haloacetronitriles (HANs) before and after the different treatments (coagulation, magnetic ion exchange (MIEX) resin, and combined MIEX/coagulation). At a low resin dose, MIEX was more effective than coagulation for DOM removal. The advantages of the MIEX resin were more prominent at a high resin dose because substantial amounts of DOM and bromide were simultaneously removed. The maximum bromide uptake on the MIEX resin was 0.02 mg-Br/mL. A 4-component PARAFAC model was developed using a dataset of 148 fluorescence excitation-emission matrices (EEMs) generated from pre-chlorinated and post-chlorinated samples. The maximum fluorescence intensities of humiclike components were found to be strongly correlated to THMs formation (R2 = 0.79-0.89). The MIEX treatment substantially lowered the formation of THMs (19-51%) and HANs (70-95%) due to its ability to remove humiclike DOM and bromide. The fluorescence loss for humic-like DOM was found to increase over a chlorination time of 3 days, suggesting that these compounds had stronger reactivity to chlorine compared to protein-like DOM. The chlorine reactivity of protein-like DOM increased after treatments as the residual chlorine was able to react with the less reactive fractions of DOM after chlorine-reactive compounds were removed.