Nanoengineering of novel MXene (Ti3C2Tx) based MgCr2O4 nanocomposite with detailed synthesis, morphology and characterization for enhanced energy storage application

Materials Science and Engineering: B(2024)

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摘要
•XRD clearly indicates both MXene and MgCr2O4 peaks within nanocomposite spectra whereas SEM s shows magnesiochromite particles attachment over MXene nanosheets.•Raman and photoluminescent spectra focused on functional groups existence alongwith maximized electron-hole recombination with bandgap value of 1.8 eV measured from UV spectra.•Peak values for C-F, C–H and MgCr2O4 are visible in FTIR spectra within range 940 cm−1, 2880 cm−1 and 505 cm−1.•Increased electrostatic repulsion designed for colloidal solution as measured by Zeta potential possess value of −19.9 mV.•EIS spectra shows maximum electron transfer rate constant value of 4.097 × 10−9 (cms−1) in IM KOH and 2.66 × 10−9 (cms−1) in 0.1 M H2SO4.•Maximum capacitance value of 542.6F/g is measured in 1 M KOH electrolyte solution at 20 mVs−1 showing its applicability as energy storage material in supercapacitors.
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关键词
MXene/MgCr2O4 nanocomposite,Electrode material,Energy-storage,Supercapacitors
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