Ce³⁺-Doped Li₂Ca₅Gd(BO₃)₅ Phosphors with Multiple Luminescent Centers and High Pressure Sensitivity under Near UV Excitation

The performance of Ce3+-based phosphors under mechanical high pressures becomes attractive due to the potential application as a visual pressure sensor. Li2Ca5Gd(BO3)(5) was selected as the host for the Ce3+ doping. Rietveld refinements reveal that rare earth cations occupy M1, M2, and M3 sites, and indeed, the photoluminescent spectra of Li2Ca5Gd1-xCex(BO3)(5) (0.005 <= x <= 0.15) exhibit the characteristic of multiple activators, defined as CeI, CeII, and CeIII, with the maximal emission wavelength at similar to 444, 419, and 378 nm, respectively. The optimal internal and external quantum efficiencies are 86.29% for x = 0.005 and 20.26% for x = 0.10, respectively, under the NUV excitation at 363 nm. In-situ high pressure emission spectra under 375 nm excitation exhibit an overall red-shift, and the linear pressure susceptibilities up to 6.7 GPa for CeI and CeII centers are -390 and -279 cm(-1)/GPa, respectively, which is probably the largest among Ce3+-doped oxides and oxysalts. Due to the above superiorities, Ce3+-doped LCGB possesses a high potential as a visual pressure sensor, and this is a successful study on the structure-property relationship of inorganic materials.