Atomistic Mechanism of Friction-Force Independence on the Normal Load and Other Friction Laws for Dynamic Structural Superlubricity

We explore dynamic structural superlubricity for the case of a relatively large contact area, where the friction force is proportional to the area (exceeding similar to 100 nm(2)) experimentally, numerically, and theoretically. We use a setup composed of two molecular smooth incommensurate surfaces: graphene-covered tip and substrate. The experiments and molecular dynamic simulations demonstrate independence of the friction force on the normal load for a wide range of normal loads and relative surface velocities. We propose an atomistic mechanism for this phenomenon, associated with synchronic out-of-plane surface fluctuations of thermal origin, and confirm it by numerical experiments. Based on this mechanism, we develop a theory for this type of superlubricity and show that friction force increases linearly with increasing temperature and relative velocity for velocities larger than a threshold velocity. The molecular dynamic results are in a fair agreement with predictions of the theory.