Plasma-assisted assembly of Co₃O₄/TiO₂-NRs for photoelectrocatalytic degradation of bisphenol A in solution and muddy systems

Herein, Co3O4/TiO2-NRs electrodes with excellent photoresponse have been prepared via the plasma-assisted modification of Co3O4 on TiO2. With the combination of Co3O4 and TiO2, the composite electrode exhibited a red-shift phenomenon and the absorption of UV and visible light were enhanced to improve the light utilization efficiency. The Mott-Schottky diagram showed that a P-N heterojunction was successfully formed between Co3O4 and TiO2 on the electrode, which inhibited the recombination of electrons and holes, and had a high photocurrent density. In our photoelectrocatalysis (PEC) degradation experiments, the degradation rates of bisphenol A (BPA) by Co3O4/TiO2-NRs electrode in Na2SO4 and simulated seawater system reached 69.44 and 100%, respectively. The important role of center dot O-2(-), center dot OH, h(+), and active chlorine (Cl-center dot, HClO/ClO-, and Cl-2) on the Co3O4/TiO2-NRs electrode during the degradation of BPA in simulated seawater was revealed. In addition, PEC combined with electrokinetic (EK) studies with the Co3O4/TiO2-NRs electrode were used for the degradation of BPA in muddy water, initially expanding the application scope of the PEC performance of the Co3O4/TiO2-NRs electrode for pollutants degradation, and had great potential for the subsequent treatment of muddy water pollutants.