Self-healing anticorrosive coatings inspired by the biomimetic porous organic cage nanocontainer for mussels
Materials Today Nano(2023)
摘要
In harsh corrosive environments such as deep sea, it cannot meet the requirements of long-term anticorrosion by uniquely increasing the physical barrier property of a coating with lamellar Ti3C2Tx nanosheets. Thus, it is quite desirable to acquire exciting anticorrosion applications through a skillful combination of a self-healing property with the physical barrier property of lamellar nanosheets. Inspired by the adhesion mechanisms of mussels, we successfully fabricated a porous organic cage (HNQ-EN) with adhesive nature as a nanocontainer. It could easily combine with Ti3C2Tx nanosheets and advance the compatibility between Ti3C2Tx and organic resin. Meantime, the porous structure of HNQ-EN enables it to accommodate various guest molecules, such as green cerium nitrate corrosion inhibitor. The introduction of HE-Ti3C2Tx-Ce in 3.5 wt% NaCl solution made the inhibition efficiency from the initial 7.8% increase to 91.1% after immersion for 36 h. It derived from the successful release of Ce3+ from HNQ-EN and forming cerium deposited film. For the composite coating containing HE-Ti3C2Tx-Ce (EP/HE-Ti3C2Tx-Ce), the LEIS results demonstrated it showed self-healing performance provided by Ce3+. Moreover, the lowest Zf = 0.01 Hz value for EP/HE-Ti3C2Tx-Ce coating reached 4.41 × 106 Ω cm2 after immersion for 36 h, which was one magnitude larger than that of EP coating.
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关键词
Porous organic cage, Nanocontainer, Self-healing, Epoxy composite coating
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