A flexible and wearable PET-based chemiresistive H2S gas sensor modified with MoS2–AgCl@AgNPs nanocomposite for the dynamic monitoring of egg spoilage

In this study, a flexible and wearable chemiresistive hydrogen sulfide (H2S) sensor is developed by modifying the MoS2–AgCl@AgNPs (MAAN) nanocomposite on a flexible PET-based Au interdigital electrode (FPAIDE) (MAAN/FPAIDE) to monitor egg spoilage at room temperature inexpensively. A new method is developed for the low-cost batch fabrication of MAAN/FPAIDEs by laser direct writing. The morphology and composition of the synthesized MAAN nanocomposite are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and transmission electron microscopy (TEM). Based on the oxygen adsorption model, a new H2S sensing mechanism is discussed, which is related to the formation of p-n junctions between MoS2 and AgCl and the specific adsorption of H2S by AgNPs on the MAAN sensing layer, causing a decrease in resistance. X-ray photoelectron spectroscopy (XPS) is used to characterize the charge transfer between gas molecules and the MAAN sensing layer and sulfide generation during the response process. The concentration of H2S can be detected down to 27 ppb at 25 °C. Finally, the prepared sensor has been successfully utilized in the real-time monitoring of egg spoilage with satisfactory results, indicating its great potential for the application of fresh food quality and safety supervision and the smart packaging of poultry eggs.