Bioinspired MOF-Glucose-PDA composite membrane with high performance and antifouling ability based on three-dimensional modification for molecular separation
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING(2023)
摘要
Membrane separation technology has been increasingly applied owing to its high efficiency and low energy consumption during resource treatment. However, the development of eco-friendly membranes with high per-formance and long-term sustainability remains a challenge. To address this issue, we designed a three-dimensional (3D)-modified biopolymer-based membrane using renewable glucose and a zirconium-based met-al-organic framework (Zr-MOF) for molecules/ions separation. The Zr-MOF and basal membrane were poly-merized at the interface using natural glucose molecules and dopamine as bridging agents to form a 3D-integrated Zr-MOF-Glucose-Polydopamine (Zr-MOF-GP) composite membrane, serving as a "green" separa-tion layer. The developed separation layer emerged additional molecular transport channels, rapid adsorption, ultrafast penetration of the solution on the surface and inside the Zr-MOF-GP composite membrane, and high molecular retention while achieving ultrahigh permeability. Moreover, the Zr-MOF-GP composite membrane exhibited excellent structural and long-term application stability in complex systems owing to the new chemical bonds formed between glucose and Zr-MOF and polydopamine substrate (synergistic effect). The experimental results demonstrated that the designed membrane exhibits superior desalination properties (99.8% Na2SO4 retention while the water flux is 31.6 L/ m2 & BULL;h & BULL;bar), good removal of heavy metal ions (69.4% for 2000 ppm Pb2+), and considerable organic solvent resistance (98.8% Rose Bengal retention while the N,N-dimethylformamide permeance is 15.6 L/ m2 & BULL;h & BULL;bar), and excellent antifouling performance. This high -performance and environment-friendly biopolymer-based composite membrane will inspire the further the development of sustainable membrane-separation technologies.
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关键词
composite membrane,mof-glucose-pda,three-dimensional
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