Bifunctionalization of carbon nitride by incorporation of thiophene ring and polar nickel complex to promote photocatalytic activity for hydrogen evolution

Photocatalytic performance of polymeric carbon nitride (CN) is primarily restricted by limited light utilization and poor charge separation efficiency. To this end, skeleton modification strategy was adopted by attaching thiophene ring and polar nickel complex (NiL) onto CN. The obtained bifunctionalized carbon nitride (TCN-NiL) displayed obviously elevated optical absorption and photoexcited charge separation efficiency. The NiL, with polar structure, plays as active sites like cocatalyst thus exhibited platinum-like H-2 evolution activity from water splitting under visible light. The optimized photocatalytic H-2 generation rate over TCN-NiL reached 136.7 mu mol center dot h(-1) without any cocatalyst, the highest rate reported so far in noble-metal-free CN-based catalysts, which is 5 times of that of CN loaded with 3 wt% Pt. Additionally, the maximum wavelength of performing H2 production capacity over TCN-NiL extends to 550 nm from 450 nm of CN, suggesting an excellent visible light absorption ability. This work provides a way for modifying CN to enhance the photocatalytic activities in a noble metal free system.