High-Performance MoS 2 /SWCNT Composite Films for a Flexible Thermoelectric Power Generator.

Single-walled carbon nanotube (SWCNT)-based thermoelectric materials have been extensively studied in the field of flexible wearable devices due to their high flexibility and excellent electrical conductivity (σ). However, poor Seebeck coefficient () and high thermal conductivity limit their thermoelectric application. In this work, free-standing MoS/SWCNT composite films with improved thermoelectric performance were fabricated by doping SWCNTs with MoS nanosheets. The results demonstrated that the energy filtering effect at the MoS/SWCNT interface increased the of composites. In addition, the σ of composites was also improved due to the reason that -π interaction between MoS and SWCNTs made good contact between MoS and SWCNTs and improved carrier transport. Finally, the obtained MoS/SWCNT showed a maximum power factor of 131.9 ± 4.5 μW m K at room temperature with a σ of 680 ± 6.7 S cm and an of 44.0 ± 1.7 μV K at a MoS/SWCNT mass ratio of 15:100. As a demonstration, a thermoelectric device composed of three pairs of p-n junctions was prepared, which exhibited a maximum output power of 0.43 μW at a temperature gradient of 50 K. Therefore, this work offers a simple method of enhancing the thermoelectric properties of SWCNT-based materials.