Molybdenum Vanadium Oxides as Intercalation Hosts for Chloroaluminate Anions

Driven by the cost and scarcity of Lithium resources, it is imperative to explore alternative battery chemistries such as those based on Aluminum (Al). One of the key challenges associated with the development of Al-ion batteries is the limited choice of cathode materials. In this work, we explore an open-tunnel framework-based oxide (Mo3VOx) as a cathode in an Al-ion battery. The orthorhombic phase of molybdenum vanadium oxide (o-MVO) has been tested previously in Al-ion batteries but has shown poor coulombic efficiency and rapid capacity fade. Our results for o-MVO are consistent with the literature. However, when we explored the trigonal polymorph of MVO (t-MVO), we observe stable cycling performance with much improved coulombic efficiency. At a charge-discharge rate of similar to 0.4C, a specific capacity of similar to 190 mAh g(-1) was obtained, and at a higher rate of 1C, a specific capacity of similar to 116 mAh g(-1) was achieved. We show that differences in synthesis conditions of t-MVO and o-MVO result in significantly higher residual moisture in o-MVO, which can explain its poor reversibility and coulombic efficiency due to undesirable water interactions with the ionic liquid electrolyte. We also highlight the working mechanism of MVO parallel to AlCl3-[BMIm]Cl parallel to Al to be different than reported previously.