Advanced Catalyst Design and Reactor Configuration Upgrade in Electrochemical Carbon Dioxide Conversion

Electrochemical carbon dioxide reduction reaction (CO2RR) driven by renewable energy shows great promise in mitigating and potentially reversing the devastating effects of anthropogenic climate change and environmental degradation. The simultaneous synthesis of energy-dense chemicals can meet global energy demand while decoupling emissions from economic growth. However, the development of CO2RR technology faces challenges in catalyst discovery and device optimization that hinder their industrial implementation. In this contribution, a comprehensive overview of the current state of CO2RR research is provided, starting with the background and motivation for this technology, followed by the fundamentals and evaluated metrics. Then the underlying design principles of electrocatalysts are discussed, emphasizing their structure-performance correlations and advanced electrochemical assembly cells that can increase CO2RR selectivity and throughput. Finally, the review looks to the future and identifies opportunities for innovation in mechanism discovery, material screening strategies, and device assemblies to move toward a carbon-neutral society. Advanced electrocatalysts and reactors are two important parallels in practical electrocatalytic carbon dioxide reduction (CO2RR). This review systematically presents the recent progress of electrocatalytic CO2RR, covering fundamental insights into a mechanism, innovative electrocatalyst design strategies based on catalyst-intermediate interaction, and the reactor optimization is also summarized to pursue high-throughput electrochemical carbon neutralization.image