Design of Ti-Pt Co-doped a-Fe2O3 photoanodes for enhanced performance of photoelectrochemical water splitting

This study demonstrates Ti and Pt co-doping can synergistically improve the PEC performance of the a-Fe2O3 photoanode. By varying the doping methods, the sample with in-situ Ti ex-situ Pt doping (Tii-Pte) exhibits the best performance. It demonstrates that Ti doping in bulk facilities charge separation and Pt doping on the surface further accelerates charge transfer. In contrast, Ti doping on the surface inhibits charge separation, and Pt doping in bulk hinders charge separation and transfer. HCl treatment is used to minimize the onset potential further, while it is favorable for the ex-situ doped a-Fe2O3, which is more efficient on Tie than the Pte-doped ones. On the ex-situ Ti-doped a-Fe2O3 after HCl treatment, anatase TiO2 is probed, suggesting that Ti-O bonds accumulate when Fe-O bonds are partly removed, which enhances the charge transfer in surface states. Unfortunately, HCl treatment also induces lattice defects that are adverse to charge transport, inhibiting the performance of in-situ doped a-Fe2O3 and excessively treated ex-situ doped ones. Coupled with methanol solvothermal treatment and NiOOH/FeOOH cocatalysts load-ing, the optimized Ti-Pt/Fe2O3 photoanode exhibits an impressive photocurrent density of 2.81 mA cm-2 at 1.23 V vs. RHE and a low onset potential of 0.60 V vs. RHE.(c) 2023 Elsevier Inc. All rights reserved.