EFFECTS OF MICROALGAL CONCENTRATION AND pH WITH FLOCCULANT ON MICROFILTRATION

Chemical Industry and Chemical Engineering Quarterly(2023)

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摘要
To make algal biomass a suitable feedstock for fuel and bioproducts, a practical way of dewatering and concentrating algal cells must be devised. In this study, a system comprising microfiltration membranes combined with a flocculant was developed on a low-cost ceramic substrate to harvest Tetradesmus obliquus efficiently. The effects of tannin-based flocculant concentration, microalgal concentration, and pH on microfiltration were studied. Permeate flux was evaluated for 5400 s through experiments to analyze the total resistance and the fouling mechanism. Results show that the cake filtration model best represented the data. The experiments at pH 4 and 0.06 kg/m3 of microalgae (with flocculant) showed improved results with a reduction in the J/J0 (permeate flux/initial flux) ratio of 39%. In addition, the effects of critical flux, transmembrane pressure, and fouling mechanism on microfiltration were investigated under the best conditions studied. Applying the stepping method to the critical flux yielded a permeate flux of 2.2 x 10-5 m3m-2s-1. The 70 kPa condition showed the highest permeate flux (3.0 x 10-5 m3m-2s-1) and a low cake pore blocking coefficient (k) obtained by the modified Hermia model. This study showed that Tanfloc at low pH could maximize in membrane
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关键词
ceramic membrane,concentration,pH,microalgal,microfiltration
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