Non-radical-dominated catalytic degradation of methylene blue by magnetic CoMoO4/CoFe2O4 composite peroxymonosulfate activators

In this study, magnetic CoMoO4/CoFe2O4 (CMO/CFO) nanospheres with a core-shell structure were synthesized via two-step hydrothermal methods. The obtained particles were employed as catalysts to activate peroxymonosulfate (PMS) and degrade methylene blue (MB). The physico-chemical characterizations of the synthesized CMO/CFO showed that the CMO shell contributed to the enhancement of redox conversion and the increase in the concentration of oxygen vacancies (OVs). By examining reactive oxygen species (ROS) in the CMO/CFO/PMS system, the MB degradation was dominated by a non-radical pathway, and 1O2 was identified as the most abundant ROS. Besides, the CMO/CFO exhibited faster reaction kinetics than the pristine CFO. Moreover, the magnetic properties guaranteed the recycling and reuse of CMO/CFO, and the removal rate of MB was maintained at ∼94% after continuous use five times. Both the tolerance to SO42−and the wide pH range where the material is applicable make it a promising catalyst for dyeing wastewater treatment.