An Electrochemical‐Electret Coupled Organic Synapse with Single‐Polarity Driven Reversible Facilitation‐to‐Depression Switching

Neuromorphic engineering and artificial intelligence demands hardware elements that emulates synapse algorithms. During the last decade electrolyte-gated organic conjugated materials have been explored as a platform for artificial synapses for neuromorphic computing. Unlike biological synapses, in current devices the synaptic facilitation and depression are triggered by voltages with opposite polarity. To enhance the reliability and simplify the operation of the synapse without lowering its sophisticated functionality, here, an electrochemical-electret coupled organic synapse (EECS) possessing a reversible facilitation-to-depression switch, is devised. Electret charging counterbalances channel conductance changes due to electrochemical doping, inducing depression without inverting the gate polarity. Overall, EECS functions as a threshold-controlled synaptic switch ruled by its amplitude-dependent, dual-modal operation, which can well emulate information storage and erase as in real synapses. By varying the energy level offset between the channel material and the electret, the EECS's transition threshold can be adjusted for specific applications, e.g., imparting additional light responsiveness to the device operation. The novel device architecture represents a major step forward in the development of artificial organic synapses with increased functional complexity and it opens new perspectives toward the fabrication of abiotic neural networks with higher reliability, efficiency, and endurance.