Insight into the Evolution of Ordered Mesoporous sp 2 Carbonaceous Material Derived from Self-Assembly of a Block Copolymer.

Block-copolymer-derived ordered mesoporous carbon (OMC) materials have great potential in many applications, such as adsorption, catalysis, and energy conversions; however, their formation process and the kinetic mechanism remain unclear. Herein, a N-doped OMC (N-OMC) with sp-bonded C atoms is developed via self-assembly of the polystyrene--poly(4-vinyl pyridine) block copolymer. By correlating the external morphologies with the internal chemical states, the formation process can be concluded as follows: (1) pore evolution via polystyrene domain degradation and (2) regularization and graphitization of the residual carbon via the removal of sp C atoms. In addition, the thickness of the N-OMC shows a power function relationship with the spin-coating rate, and the N content can be incredibly increased up to 26.34 at. % in an NH carbonization atmosphere. With the as-prepared N-OMC as the support for loading of the pseudo-atomic-scale Pt (Pt/N-OMC), a high electrochemical active surface area value of 99.64 m·g and a half-wave potential () of 0.850 V are achieved, showing great potential in developing single-atom electrocatalysts.