An Ultra-Stretchable Polyvinyl Alcohol Hydrogel Based on Tannic Acid Modified Aramid Nanofibers for Use as a Strain Sensor

The mechanical performance is critical for hydrogels that are used as strain sensors. p-Aramid nanofiber (ANF) is preferable as an additive to the reinforce the mechanical performance of a poly(vinyl alcohol) (PVA). However, due to the limited hydrogen bond sites, the preparation of ultra-stretchable, ANF-based hydrogel strain sensor is still a challenge. Herein, we reported an ultra-stretchable PVA hydrogel sensor based on tea stain-inspired ANFs. Due to the presence of numerous phenol groups in the tannic acid (TA) layer, the interaction between PVA and the ANFs was significantly enhanced even though the mass ratio of TA@ANF in the hydrogel was 2.8 wt parts per thousand. The tensile breaking modulus of the PVA/TA@ANF/Ag hydrogel sensor was increased from 86 kPa to 326 kPa, and the tensile breaking elongation was increased from 356% to 602%. Meanwhile, the hydrogel became much softer, and no obvious deterioration of the flexibility was observed after repeated use. Moreover, Ag NPs were formed in situ on the surfaces of the ANFs, which imparted the sensor with electrical conductivity. The hydrogel-based strain sensor could be used to detect the joint movements of a finger, an elbow, a wrist, and a knee, respectively. This ultra-stretchable hydrogel described herein was a promising candidate for detecting large-scale motions.