Ultrafiltration significantly increased the scaling potential of municipal secondary effluent on reverse osmosis membranes.

Ultrafiltration (UF) was often used as pretreatment in front of reverse osmosis (RO) unit because of its high rejection efficiency of microbes and particles. However, in some cases UF pretreatment might show adverse effects on the RO membrane flux. In this study, the effects of UF pretreatment on secondary effluent water quality and its RO membrane fouling characteristics were explored. There was almost no change of water quality after UF with different molecular weight cut-off (MWCO) membranes (100, 30 and 10 kDa), including total dissolved solid (TDS), alkalinity, conductivity, ion concentrations, etc., while pH increased a little and dissolved organic carbon (DOC) declined by about 1 mg/L. On the contrary, the RO membrane flux of UF permeates presented clear decline in comparison to the secondary effluent. The membrane fouling velocity and steady-state flux of secondary effluent was 0.052 and 0.656, while fouling velocity increased (0.077, 0.071, 0.067) and steady-state flux decreased significantly (0.397, 0.416, 0.448) after 100, 30, 10 kDa UF membrane pretreatment. Scanning electron microscope (SEM) images showed many crystals on the fouled membrane surfaces, which turned out to be CaCO3 by Energy dispersive spectrometer (EDS) analysis and precipitation calculation. After the addition of UF retentates to UF permeates, scaling was prevented and crystals on the RO membrane almost disappeared, which implied the anti-scaling effect of the UF retentates with low concentration. According to anti-scaling performance experiments, the anti-scaling performance of 100 k, 30 k, 10 k retentates was 2.7%, 4.0% and 7.3%, respectively. Excitation emission matrix (EEM) and fourier transform infra-red (FTIR) results showed that these retentates retained by different MWCO membranes were similar and composed of protein-like substances and soluble microbial products. The effect of key minority components in RO system deserved further exploration.