Construction of novel cluster-baseed MOF as multifunctional platform for CO2 catalytic transformation and dye selective adsorption

Synthetic conditions and ligands are the key structural defining factors of metal–organic frameworks (MOFs). Therefore, reasonable optimization of these aspects is considered to be an effective means for designing materials with novel structures and target functions. Herein, two novel Co(II)-based MOFs, namely [Co(HL)(dibp)] n ( HL-8 ) and {[Co 2 (L)(OH)(dibp)]•DMA} n ( HL-9 ) (H 3 L = 2′,6′-dimethyl-[1,1′-biphenyl]-3,4′,5-tricarboxylic acid; dibp = 4,4′-di(1 H -imidazol-1-yl)-1,1′-biphenyl]), have been hydrothermally synthesized and structurally characterized. HL-8 crystallizes in the orthorhombic system ( Pna 2 1 ) with a grid layer structure, while HL-9 crystallizes in the monoclinic P 2 1 / n space group assembled through Co 4 (OH) 2 clusters with organic ligands. Remarkably, benefiting from the finite cage-like structure, HL-9 exhibited enhanced performance in carbon dioxide (CO 2 ) adsorption/catalytic transformation and excellent size selectivity during dye molecular adsorption process. A novel metal-organic framework functionalized with a rare Co 4 cluster and finite cages was successfully afforded, which exhibits enhanced performance in carbon dioxide adsorption/catalytic transformation as well as excellent size selectivity in dye molecular adsorption process.