Effect of Different Solutions on the Colour Stability of Nanoparticles or Fibre Reinforced PMMA

POLYMERS(2022)

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摘要
This study aimed to evaluate the colour stability of polymethyl methacrylate (PMMA) denture base reinforced with ZrO2 nanoparticles, E-glass fibres, and TiO2 nanoparticles at various concentrations over 180-day storage in SteradentTM (STD) denture cleaner or coffee (CF). A total of 130 disc-shaped specimens were fabricated at various filler concentrations and divided into four main groups to measure the colour changes. Groups Z, T, and E consisted of PMMA reinforced with ZrO2 nanoparticles, TiO2 nanoparticles, or E-glass fibre, respectively, while Group C consisted of PMMA specimens without filler served as the control group (n = 10). The three reinforced groups were further subdivided according to the filler content (n = 10) added to the PMMA (1.5%, 3.0%, 5.0%, and 7.0% wt.%). Half of the specimens were stored in STD, while the other half was stored in CF for 180 days. A Minolta Chroma Meter was used to measure the colour changes (AE) at 7, 30, 90 and then 180 days. The results were assessed using two-way repeated-measures analysis of variance (RM-ANOVA) along with Bonferroni post hoc tests at a p <= 0.05 significance level. Significant different colour changes (Delta E) were observed between all tested groups and across different time points. TiO2 -reinforced PMMA in STD/CF showed the lowest colour stability, while the E-glass fibre-reinforced PMMA in STD/CF showed the highest colour stability. Furthermore, coffee appeared to have the greatest impact on the colour change in comparison to the Steradent TM . The results indicated that the filler type and concentration, type of solution, and length of storage all affected the colour stability of the tested specimens.
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关键词
PMMA, ZrO2 nanoparticle, TiO2 nanoparticle, E-glass fibre, colour stability, Steradent (TM), coffee
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