Overcoming the Selectivity-Permeability Trade-Off with Nanoporous Carbon Nanotube Membranes

From energy storage to separation applications, performances of nanoporous membranes are typically limited by an inherent trade-off between transport rate and selectivity. For example, conventional protective garments sacrifice breathability to prevent exposure to harmful agents, and this trade-off severely hinders the duration of their active use. The discovery of enhanced fluid flow in single-walled carbon nanotubes (SWCNT) has provided a path toward combining the diametric properties of high selectivity and permeability into a single SWCNT-based material, yet successful demonstration of this promise remains elusive. Using as example the design of novel materials for protective clothing applications, herein we demonstrate a smart, nanoporous, SWCNT membrane that overcomes the limitation of conventional protective garments. Specifically, we show that the adoption of nanometer-wide SWCNTs for ultrafast moisture conduction [1] enables a simultaneous boost in size-sieving selectivity and water-vapor permeability by decreasing nanotube diameter, thereby overcoming the breathability/protection trade-off [2].Our membrane platform can rapidly and selectively transition from a highly breathable state in a safe environment to a protective state when exposed to a chemical threat. Dynamic response to chemical stimuli is achieved through the physical collapse of an ultrathin copolymer layer on the membrane surface, which efficiently gates transport through the SWCNT membrane pores [2].Multifunctional SWCNT membranes such these present exciting opportunities in many other areas including energy-efficient separations, energy storage, and smart delivery. References 1. N. Bui, E. R. Meshot, S. Kim, J. Peña, P. W. Gibson, K. J. Wu, F. Fornasiero, Adv. Mater., 28 (2016) 5871. 2. Y. Li, C. Chen, E. R. Meshot, S. F. Buchsbaum, M. Herbert, R. Zhu, O. Kulikov, B McDonald, N. Bui, M. L. Jue, S. J. Park, C. Valdez, S. Hok, C. J. Doona, K. J. Wu, T. M. Swager, F. Fornasiero, submitted (2019) This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.