Toner processes using sodum sulfonated polyester resns background of the invention

POLYESTER RESNS,Guerino G. Sacripante, Raj D. Patel, O. Palazzo, IIHIII

semanticscholar(2017)

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摘要
A process for the preparation of toner compositions com prising: (i) preparing an emulsion latex comprised of sodio sul fonated polyester resin particles of from about 5 to about 500 nanometers in size diameter by heating said resin in water at a temperature of from about 65° C. to about 90° C. (ii) preparing a pigment dispersion in a water by dispers ing in water from about 10 to about 25 weight percent of sodio sulfonated polyester and from about 1 to about 5 weight percent of pigment; (iii) adding the pigment dispersion to a latex mixture comprised of sulfonated polyester resin particles in water with shearing, followed by the addition of an alkali halide in water until aggregation results as indi cated by an increase in the latex viscosity of from about 2 centipoise to about 100 centipoise; (iv) heating the resulting mixture at a temperature of from about 45° C. to about 80° C. thereby causing further aggregation and enabling coalescence, resulting in toner particles of from about 4 to about 9 microns in volume average diameter and with a geometric distri bution of less than about 1.3; and optionally (v) cooling the product mixture to about 25° C. and followed by washing and drying.
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