LeTID mitigation via an adapted firing process in p-type PERC cells from SMART cast-monocrystalline, Czochralski and high-performance multicrystalline silicon

PROGRESS IN PHOTOVOLTAICS(2022)

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摘要
In this work, we analyse passivated emitter and rear cells (PERC), based on wafers made from seed manipulation for artificially controlled defects technique (SMART) monocrystalline silicon, magnetically grown and conventional Czochralski (mCz and Cz) silicon, and high-performance multicrystalline (hpm) silicon. All wafers were processed identically except for the hpm wafers, which received an acidic texture instead of random pyramids. The energy conversion efficiency eta of the SMART cells of 21.4 % is similar to the mCz cells (21.5 %) while being more than 1.9%abs higher than for the hpm cells. Furthermore, we here show for the first time that light- and elevated temperature-induced degradation (LeTID) is mitigated in hpm, Cz and SMART PERC cells without significant losses in initial efficiency by an adapted fast-firing process, incorporating slower firing ramps that can be used in industrial production. The cells that are fired with these ramps show no significant efficiency loss ( 1%rel更多
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关键词
carrier-induced degradation (CID), fast-firing oven (FFO), light- and elevated temperature-induced degradation (LeTID), mitigation, passivated emitter rear contact (PERC), seed manipulation for artificially controlled defects technique (SMART)
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