First Stereoselective Total Synthesis Of Ciryneol C

Ambati Sharada,Lakshmi Srinivasa Rao Kundeti,Kallaganti V. S. Ramakrishna,Kommu Nagaiah

SYNOPEN（2019）

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摘要

The acetylene derivative Ciryneol C was isolated from the roots of C. japonicum. The asymmetric total synthesis of Ciryneol C was achieved in seven steps, with Horner-Wittig olefination, regioselective epoxide opening, and Cadiot-Chodkiewicz coupling reactions being the key steps.

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关键词

acetylene, Cadiot-Chodkiewicz coupling, natural products, Sharpless asymmetric epoxidation, total synthesis

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