Biobased sustainable materials made from starch and plasma/ultrasound modified Agave fibers: Structural and water barrier performance

This study aims to investigate the effect of green modification methods (ultrasound and plasma treatment) on a by-product of the tequila industry (Agave fibers), which can be useful as raw material to elaborate biodegradable and hydrophobic starch films. FTIR analysis indicated a decrease of hydrophilic lignocellulosic components, since the cavitation and etching effect of ultrasound/plasma treatment reduced the large number of hydroxyl groups of the fibers. The inclusion of ultrasound/plasma modified fibers in the starch matrix limited the starch-glycerol interactions, reducing the free volume of the starch and the binding sites for water. Therefore, the solubility (%5), swelling (%W) and water vapor permeance (WVPe) of the films decreased from 27 to 16%, 57 to 50% and 0.37 to 0.21 g/day m(2)Pa, respectively. Furthermore, the water contact angle (WCA) and relative crystallinity values increased. The results indicated that the treatments are suitable green technologies to obtain hydrophobic fillers useful to develop sustainable materials.