Effect of thermite on the infrared radiation performance of Mg4Al3/PTFE/Viton agents

Journal of Energetic Materials(2023)

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摘要
To improve the infrared radiation performance of the Mg4Al3/PTFE/Viton agents (MATV), three higher energy magnesium thermite, Mg-Fe2O3, Mg-MnO2 and Mg-MoO3, were selected and added to the MATV. Thermal analysis and X-ray diffraction were used to explore the agents' reaction processes, and infrared thermography was used to examine their combustion radiation characteristics. The results demonstrate that the thermite reaction starts after the MATV reaction and the reaction region is in the aerobic zone. All three thermites can accelerate the burning rate of MATV, and the effect is Mg-Fe2O3> Mg-MoO3> Mg-MnO2. Mg-Fe2O3 increased the infrared radiation intensity of MATV agents by 43.5% in the 2 similar to 5.5 mu m band and 45.1% in the 8 similar to 14 mu m band at 40% content. The effect of Mg-MoO3 on radiation area enhancement is significant, with a 107% expansion of radiation area at 70% content. The addition of thermite improves the combustion performance and radiation performance of MATV, which offers good application prospects.
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关键词
Combustion,infrared radiation,MATV,pyrotechnics,thermite
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