Zircon U–Pb geochronology and geochemistry of the Lajimiao mafic complex in the Shangdan Suture Zone, Qinling orogen: Petrogenesis and tectonic implications

The Shangdan Ocean represents the eastern branch of the Proto-Tethys Ocean, which is important to decipher the evolution of the Central China Orogenic Belt. However, its evolution is still in debated. In this contribution, we carried out an integrated study of zircon UPb ages, whole-rock geochemistry, as well as zircon HfO isotope compositions for the Lajimiao mafic complex in the Shangdan Suture Zone in the North Qinling orogen. The Lajimiao mafic complex is composed of coarse-grained gabbros to norite-gabbros (Group 1) in the inner and fine-grained diorites (Group 2) in the outer part. The Group 1 samples are comprised predominantly of salite to augite (Mg# = 75–80), magnesi-hornblende (Mg# = 65–67) and Ca-rich plagioclase (An = 45–67); the Group 2 samples are comprised predominantly of magnesi-hornblende (Mg# = 60–66) and plagioclase (An = 28–53). New SIMS and LA-ICP-MS UPb dating of zircon grains from a gabbro and a diorite sample yielded similar weighted mean ages of 412 ± 4 Ma and 414 ± 2 Ma, indicating that they were formed simultaneously. The Group 1 samples have relatively low SiO2 (49.56–50.78 wt%), high MgO (6.67–7.70 wt%) and Fe2O3T (7.46–9.61 wt%) contents, while the Group 2 samples have relatively high SiO2 (57.74–59.53 wt%), low MgO (3.28–3.42 wt%) and Fe2O3T (5.76–7.01 wt%) contents. They both belong to calc-alkalic series and enriched in large ion lithophile elements (LILEs), light rare earth element (LREEs) and depleted in high field strength elements (HFSEs), which are typical of arc-related rocks. The Group 2 diorites exhibit relative enrichment in light rare earth element (LREE) ((La/Yb)N = 10.9–13.1) with slightly negative Eu anomalies (Eu/Eu⁎ = 0.82–0.93), compared to the Group 1 samples ((La/Yb)N = 5.2–9.6; Eu/Eu⁎ = 0.91–1.43). Both of them have enriched initial Sr (0.7049–0.7054), and chondritic to slightly depleted Nd (ƐNd(t) = −0.09 ~ +1.50), but depleted whole-rock and zircon Hf isotopic compositions (ƐHf(t) = 7.81–8.10 and 8.2–9.1). The HfNd isotopic systems are decoupled with positive △ƐHf values (5.22 to 5.92) (△ƐHf = ƐHf(t) – (1.59 × ƐNd(t) + 1.28)). The zircon grains display higher δ18O values of 6.3 to 6.5‰ than those of the normal mantle zircon. Whole-rock Pb isotopic compositions of the studied samples are of 15.610–15.624 for 207Pb/204Pb, 38.027–38.178 for 208Pb/204Pb, and 18.100–18.269 for 206Pb/204Pb. These geochemical features indicate that the Lajimiao mafic complex was derived from relatively depleted mantle that had been metasomatized by 2–5% subducted zircon-barren oceanic sediments. Combining with regional geological, geochronological, mineralogical, and geochemical data, the Lajimiao mafic complex was suggested to be generated by partial melting of a phlogopite-bearing mantle source at relatively low pressure in an arc setting. We suggested that the generation of the Lajimiao mafic complex was induced by the subduction of Shangdan Ocean during the early Devonian and thus the eastern branch of Proto-Tethys Ocean might have not been closed until that time.