Resistance To Molten Superalloy At 1550 Degrees C For Molybdenum Metal Core With A Silica/Silicide Coating

This work designs a silica (SiO2) layer on a molybdenum metal core to provide new insights on the corrosion resistance of the silica/silicide coating in the Ni-based superalloy. The molybdenum substrate coated with MoSi2 by pack cementation was pre-oxidized to fabricate a cristobalite scale on the surface and the preoxidation specimens were chosen to examine the corrosion-resistant property by using a DSM11 superalloy at 1550 degrees C. In order to prepare a cristobalite layer, the microstructure evolution of a 40- mu m MoSi2 coating with the different oxidation parameters (temperature and time) was investigated. After casting test, the different casting results showed that the silicide layer was dissolved in the molten superalloy. However, the molybdenum matrix was found to be protected by the cristobalite layer, as well as accompanied by the cristobalite layer partially destroyed at the core/superalloy interfaces. Furthermore, the reason for the destruction of cristobalite layer was analyzed. The failure mechanism of the cristobalite layer was proposed during the cast process.