In-plane heterostructured Ag 2 S-In 2 S 3 atomic layers enabling boosted CO 2 photoreduction into CH 4

Sluggish separation and migration kinetics of the photogenerated carriers account for the low-efficiency of CO 2 photoreduction into CH 4 . Design and construction two-dimensional (2D) in-plane heterostructures demonstrate to be an appealing approach to address above obstacles. Herein, we fabricate 2D in-plane heterostructured Ag 2 S-In 2 S 3 atomic layers via an ion-exchange strategy. Photoluminescence spectra, time-resolved photoluminescence spectra, and photoelectrochemical measurements firmly affirm the optimized carrier dynamics of the In 2 S 3 atomic layers after the introduction of in-plane heterostructure. In-situ Fourier transform infrared spectroscopy spectra and density functional theory (DFT) calculations disclose the in-plane heterostructure contributes to CO 2 activation and modulates the adsorption strength of CO* intermediates to facilitate the formation of CHO* intermediates, which are further protonated to CH 4 . In consequence, the in-plane heterostructure achieves the CH 4 evolution rate of 20 µmol·g −1 ·h −1 , about 16.7 times higher than that of the In 2 S 3 atomic layers. In short, this work proves construction of in-plane heterostructures as a promising method for obtaining high-efficiency CO 2 -to-CH 4 photoconversion properties.