Largely Color-Tuning Prompt And Delayed Fluorescence: Dinuclear Cu(I) Halide Complexes With Tert-Amines And Phosphines

Luminescent copper(I) halide complexes with bi- and tridentate rigid ligands have gained wide research interests. In this paper, six tetracoordinate dinuclear copper(I) halide complexes, Cu2X2(ppda)(2) [ppda = 2-[2-(dimethylamino)phenyl(phenyl)phosphino]-N,N-dimethylaniline, X = I (1), Br (2), Cl (3)] and Cu2X2(pfda) 2 [pfda = 2-[2(dimethylamino)-4-(trifluoromethyl)phenyl(phenyl)phosphino]-N,N-di-methyl-5-trifluoromethylaniline, X = I (4), Br (5), Cl (6)], were successfully prepared and systematically characterized on their structures and photo-physical properties. Complexes 1-5 have a centrosymmetric form with a planar Cu2X2 unit, and complex 6 has a mirror symmetry form with a butterfly-shaped Cu2X2. Solid complexes 1, 4, and 5 emit delayed fluorescence at room temperature, intense blue to greenish yellow (lambda(max) = 443-570 nm) light, and their peak wavelengths are located at 443-570 nm with microsecond lifetimes (t = 0.4-19.2 mu s, FPL = 0.05-0.48). Complexes 2, 3, and 6 show prompt fluorescence, very weak yellowish green to yellow (lambda(max) = 534-595 nm) emission with peak wavelengths at 534-595 nm, and lifetimes in nanoseconds (t = 4.4-9.3 ns, FPL < 0.0001). (Metal + halide) to ligand and intraligand charge transitions are the main origin of the emission of the complexes. Solution-processed, complex-4-based nondoped and doped devices emit yellow green light with CIE coordinated at (0.41, 0.51), a maximum EQE up to 0.17%, and luminance reaching 75.52 cd/m(2).