Spatiotemporal characteristics and pollution level of brominated flame retardants in bivalves from Fujian southern coastal areas

The concentration and spatiotemporal distribution of brominated flame retardants (BFRs), including hexabromocyclododecane (HBCD) and tetrabromobisphenol A (TBBPA), were analyzed in bivalves from Fujian southern coastal areas. The concentrations of HBCD and TBBPA ranged from ND (not detected) to 5.540 ng·g −1 (ww) (median of 0.111 ng·g −1 ) and ND to 0.962 ng·g −1 (ww) (median of ND), respectively. In addition, α-HBCD was found as the predominant diastereoisomer in all the studied samples, followed by β-HBCD and γ-HBCD. The spatial distribution of BFRs showed a peak distribution, with the content being higher in the marine environment of Xiamen and Quanzhou, in South Fujian, and lower toward the marine environment of Zhangzhou, and Putian. BFRs contamination level was correlated to the bay geographical location and proximity to local industries. Furthermore, the results of the study showed a seasonal variation pattern: summer > autumn > spring > winter. This study provides base information on the contamination status of these BFRs in the marine environment of southern Fujian.