Reaction Characteristics And Kinetics Of The Low-Temperature Oxidation And Weight Gain Of Coal

The study of coal oxidation and weight gain at low temperatures is helpful in understanding the spontaneous combustion of coal and its mechanisms. In this study, we comprehensively investigated the low-temperature oxidation properties and the oxygen adsorption weight gain kinetics of Chinese Shenhua subbituminous coal (SH). Using thermogravimetric experiments with various particle sizes, heating rates, and coal ranks, the oxygen adsorption mass gain stages of coal oxidation at low temperatures were investigated. According to the results of these experiments, as the particle size of SH coal decreased, the dry cracking temperature (T1) decreased, the ignition temperature (T2) changed slightly, the weight gain increased, and the spontaneous combustion tendency increased. The three-dimensional diffusion model (Zhuralev-Lesokin-Tempelman) (D5) is suitable for SH coal samples with different particle sizes. A higher heating rate is not conducive to the formation of carbon-oxygen complexes. The D5 model can also be used to fit the kinetics of the SH coal samples at 5 K/min, 10 K/min, and 30 K/min. Unlike the SH coal samples, the Shengli lignite (SL) and Tavan Tolgoi anthracite (TT) samples fit the three-dimensional diffusion model (Jander) (D3). Based on the fitting results of the Achar differential method and the Coats-Redfern integral method, the activation energyEof the low-temperature oxidation weight gain of the coal samples decreases with decreasing coal particle size and with increasing oxidation rate and coal rank.