Thermodynamic study of a phase-change solvent: New experimental data and modelling

Y. Coulier,K. Ballerat-Busserolles,L. Rodier,J-Y. Coxam

Thermochimica Acta（2020）

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摘要

•LLE data were measured for 2,4,6-tris(dimethylaminomethyl)phenol – water system.•CpE" /> and VE were determined for 2,4,6-tris(dimethylaminomethyl)phenol – water system.•Extended scaling law allows the representation of the LLE data.•VE are correlated using Redlich-Kister equation.•Activity coefficient models were used to represent phase equilibria and energetic properties.

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关键词

Density,Liquid–liquid equilibrium,Specific heat capacity,Thermodynamic modeling,Excess enthalpy

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